After boxing with my 100 SK, pulling for several weeks I'm pretty happy with this .ini. My Holyshits are below as well (work in progress).
INI:
[General]
KissAssistVer=7.1
[SpellSet]
LoadSpellSet=2
[Buffs]
BuffsOn=1
Buffs1=Call of Gloomhaze Rk. II
Buffs2=Shroud of the Darksworn Rk. II
Buffs3=Falhotep's Covenant Rk. II
Buffs4=Zombie Skin Rk. II
Buffs5=Grelleth's Horror Rk. II
Buffs7=Drape of the Fallen Rk. II
Buffs8=Ring of Stolen Graves
Buffs10=Darkened Flowing Black Silk Sash|0
Buffs11=Voice of Thule|Me
Buffs12=Glyph of Courage
Buffs13=Nightwing Fang Earring
Buffs14=Engraved Butterfly Faceguard
Buffs15=Shoon's Hide Poncho
Buffs16=Dimensional Warrior Gorget
Buffs17=Rest|20|End
Buffs20=Vial of Caustic Fluid
RebuffOn=1
CheckBuffsTimer=20
[AE]
AEOn=1
AERadius=50
[DPS]
DPSOn=1
DPSSkip=20
DPSInterval=2
DPS1=Encroaching Darkness|40
DPS2=Blood of Ralstok Rk. II|80
DPS3=Plague of Klonda Rk. II|85
DPS4=Surreptitious Blight Rk. II|90
DPS5=Chattering Bones|90
DPS6=Ragged Bite of Agony|85
DPS7=Vicious Bite of Chaos|63
DPS8=Terror of Poira Rk. II|99|Once
DPS9=Improved Explosion of Hatred|98
DPS10=Improved Explosion of Spite|40
DPS12=Spear of Grelleth Rk. II|30
DPS13=Torrent of Agony|97
DPS14=Dire Stricture Rk. II|96
DPS15=Demand for Power Rk. II|80
[Pull]
PullWith=Demand for Power Rk. II
[Heals]
HealsOn=1
Heals1=Dire Insinuation Rk. II|60|Tap
Heals2=Reprove|30|Me
[Cures]
CuresOn=1
Cures1=Purity of Death
[Pet]
PetOn=1
PetSpell=Minion of Grelleth Rk. II
PetBuffsOn=1
PetBuffs1=Gift of Falsin Rk. II|0
INI:
downshit0=/if (!${Me.Buff[Steadfast Stance Rk. II].ID} && !${Me.CombatState.Equal[COMBAT]} && ${Me.PctMana}>80 && ${Cast.Ready[Steadfast Stance Rk. II]} && ${Spell[Steadfast Stance Rk. II].Stacks} && !${Me.Moving}) /casting "Steadfast Stance Rk. II" gem11 -invis
downshit1=/if (!${Me.Buff[Grelleth's Skin Rk. II].ID} && !${Me.CombatState.Equal[COMBAT]} && ${Me.PctMana}>80 && ${Cast.Ready[Grelleth's Skin Rk. II]} && ${Spell[Grelleth's Skin Rk. II].Stacks} && !${Me.Moving}) /casting "Grelleth's Skin Rk. II" gem10 -invis
holyshit0=/if (${Target.Named} && ${Me.AltAbilityReady[Fundament: Third Spire of the Reavers]}) /alt act 1452
holyshit1=/if (${Me.CombatAbilityReady[Grelleth's Carapace Rk. II]} && ${Target.Named} && ${Me.CurrentEndurance}>8000 && ${Window[CombatAbilityWnd].Child[CAW_CombatEffectLabel].Text.Equal[No Effect]}) /disc Grelleth's Carapace Rk. II
holyshit2=/if (${Me.CombatAbilityReady[Bonebrood Mantle]} && ${Target.Named} && !${Me.CombatAbilityReady[Grelleth's Carapace Rk. II]} && ${Me.CurrentEndurance}>8000 && ${Window[CombatAbilityWnd].Child[CAW_CombatEffectLabel].Text.Equal[No Effect]}) /disc Bonebrood Mantle
holyshit3=/if (${Me.CombatAbilityReady[Unholy Guardian Discipline Rk. II]} && !${Me.CombatAbilityReady[Bonebrood Mantle]} && ${Target.Named} && !${Me.CombatAbilityReady[Grelleth's Carapace Rk. II]} && ${Me.CurrentEndurance}>8000 && ${Window[CombatAbilityWnd].Child[CAW_CombatEffectLabel].Text.Equal[No Effect]}) /disc unholy Guardian Discipline Rk. II
holyshit4=/if (${Target.Named} && !${Me.Song[Lich Sting Recourse].ID}) /casting "Innoruuk's Dark Blessing"|Item
holyshit5=/if (${Target.Named} && ${Me.AltAbilityReady[Visage of Death]}) /alt act 9403
holyshit6=/if (${Target.Named} && ${Me.AltAbilityReady[Harm Touch]}) /multiline ; /alt act 6000 ; /alt act 1277 ; /alt act 651 ; /alt act 3822
holyshit7=/if (${Target.Named} && ${Me.AltAbilityReady[Leech Touch]}) /alt act 87
holyshit8=/if (${Target.Named} && ${Me.AltAbilityReady[Gift of the Quick Spear]}) /multiline ; /alt act 2034 ; /alt act 1278
holyshit9=/if (${Me.CombatAbilityReady[Scarlet Blade]} && ${Me.Buff[Visage of Death].ID}) /disc "Scarlet Blade Rk. II"
holyshit10=/if (${Target.Named} && ${Me.AltAbilityReady[Glyph of the Cataclysm]}) /alt act 7019
holyshit11=/if (${Target.Named} && !${Me.AltAbilityReady[Glyph of the Cataclysm]} && ${Me.AltAbilityReady[Glyph of Destruction]}) /alt act 589
holyshit12=/if (${Target.Named} && !${Me.AltAbilityReady[Glyph of the Cataclysm]} && !${Me.AltAbilityReady[Glyph of Destruction]} && ${Me.AltAbilityReady[Glyph of Courage]}) /alt act 5000
holyshit13=/if (!${Target.Named} && ${Mercenary.State.Equal[ACTIVE]} && ${Mercenary.Stance.NotEqual[Balanced]} && ${Mercenary.Class.Name.Equal[Cleric]}) /stance balanced
holyshit14=/if (${Target.Named} && ${Mercenary.State.Equal[ACTIVE]} && ${Mercenary.Stance.NotEqual[Reactive]} && ${Mercenary.Class.Name.Equal[Cleric]}) /stance reactive