Here is what I was using at 100 and it worked decently. I have to say KA is a great group program and works ok healing a single group on a raid, but if you're going to truly raid you either need to write your own custom script to heal the way you would on a raid; or look for a raid specific macro. KA will heal group + a tank, but it's not weighted for raiding. Just change these to 105 spells. When I actually get my 100 cleric the expansion I'll work on the new INI. For now though, I haven't bought anyone but my main the expansion.
ini:
[General]
KissAssistVer=7.4
[SpellSet]
LoadSpellSet=2
[Buffs]
BuffsOn=1
Buffs1=Divine Interposition Rk. III|Melee
Buffs2=Quiet Miracle|Mana|55
Buffs3=Shining Bastion Rk. II|MA
Buffs4=Summoned: Large Modulation Shard|Mana|85
Buffs5=Veturika's Perseverance|Mana|70
Buffs6=Aura of Divinity|Aura
Buffs7=Unified Hand of Gezat RK. II|Dual|Symbol of Gezat RK. II
Buffs8=Rallied Bastion of Vie
Buffs9=Armor of the Reverent Rk. II|Me
Buffs10=Aura of the Reverent Rk. II|Aura
RebuffOn=1
CheckBuffsTimer=10
[DPS]
DPSOn=1
DPSSkip=0
DPSInterval=0
DPS1=Divine Interposition Rk. III|99|MA
DPS2=Shining Bastion Rk. II|99|MA
DPS3=Yaulp XIII Rk. II|99
[Aggro]
AggroOn=1
Aggro1=Divine Peace|99|>
[Heals]
HealsOn=1
Heals1=Fifteenth Emblem Rk. III|45
Heals2=Burst of Life|45
Heals3=Beacon of Life|45
Heals4=Graceful Remedy Rk. III|45|!MA
Heals5=Forceful Rejuvenation|45
Heals6=Graceful Remedy Rk. III|95|MA
Heals7=Virtuous Intervention Rk. III|95|MA
Heals8=Fraught Renewal Rk. II|95|MA
Heals9=Fervent Renewal|95|MA
Heals10=Frenzied Renewal Rk. II|95|MA
Heals11=Word of Reformation|99
AutoRezOn=0
AutoRezWith=NULL
[Cures]
CuresOn=1
Cures1=Radiant Cure
Cures2=Group Purify Soul
Cures3=Word of Reformation
[Burn]
BurnAllNamed=0
Burn1=Fundament: Third Spire of Divinity
Burn2=Focused Celestial Regeneration|MA
Burn3=Celestial Rapidity
Burn4=Flurry of Life
Burn5=Healing Frenzy
Burn6=Gelid Illuminator Breastplate